 |
 |
|
 |
 |
|
|
 |
|
After extraction, coal is washed and sorted.
Depending on its type, the coal will be burned (domestic heating, industrial boilers, coal-fired power plants) or transformed into coke.
Coke is concentrated coal
from which the majority of volatile materials have been eliminated. In a coking plant, a mixture of good quality coal types, known as coke paste, is brought up to a temperature of 1000°C. The coking process liberates a number of products, mainly pyrolysed gases, which are cooled and treated with solvents.
In this way, some of the gases are recovered. The liberated products are:
- The tars;
- The essences from which benzol is extracted. Benzol is a mixture of aromatic hydrocarbons (benzene, toluene and xylene);
- Methane, which is dispatched into the gas distribution network once its impurities (hydrogen, sulphur and ammonia) have been removed.
|
|
 |
| The Forzando Mines (Witbank - South Africa). |
|
 |
|
|
|
From 1 million tons of coal, we recover 50 000 tons of tars, 15 000 tons of benzol and 500 million cubic metres of gas. The coke, a coal with a high pure carbon content, is used in blast furnaces or mixed with mineral iron to produce cast-iron (an alloy of iron and carbon, which was a forerunner of steel) by iron oxide reduction.
Large quantities of coke are rapidly produced in coking units, groups of several dozen eight metre high ovens.
Smaller pyrolysis units also exist, adapted to different types of coal. They produce special cokes, such as lignite coke, which can replace charcoal. And at a lower temperature to that of the coking process, at about 700°C, the pyrolysis process allows preservation of the heavy aromatic molecules, the phenol tars full of phenol and xylenol. After treatment, these aromatic alcohols are used in the manufacture of insecticides, fungicides, anti-oxidants and phenol-formaldehyde resins that are used as drying accelerators for varnish and ink.
Finally, in a gasification process, coal can be used to produce synthesis gas by partial oxidation in the presence of oxygen and steam. Synthesis gas is a mixture of carbon monoxide and hydrogen. It is used as an intermediate reagent leading to different products (methanol, urea, pure hydrogen, dimethylether) according to the synthesis route chosen, and above all to synthetic fuels by the Fischer-Tropsch reaction, named after its two German inventors (in the 1920’s). In this case the product obtained is a wax containing a multitude of paraffin-type hydrocarbons with a very variable number of carbon atoms. This wax must undergo a hydro- cracking process to produce predominantly a very good quality diesel, and, in smaller quantities, LPG and petrol. Very high quality lubricating bases can also be obtained, depending on the method of operation of the hydrocracking plant. But this process is very expensive, and the production of synthesis gas from coal is exceedingly greedy in energy terms. |
| |
|
|
|
|